вот так #pragma pack(1)
typedef struct{
	unsigned char   bVar;
	unsigned short  wVar;
}t_3byte;
#pragma pack()
unsigned char   rgVar[20]={1,2,3,4,5,6,7,8,9,0};
void main(){
unsigned char   bVar, i;
unsigned short  wVar;
  i=1;
 
  bVar =  ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->bVar;
  wVar =  ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->wVar;
  i++;
  bVar =  ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->bVar;
  wVar =  ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->wVar;
}