вот так #pragma pack(1)
typedef struct{
unsigned char bVar;
unsigned short wVar;
}t_3byte;
#pragma pack()
unsigned char rgVar[20]={1,2,3,4,5,6,7,8,9,0};
void main(){
unsigned char bVar, i;
unsigned short wVar;
i=1;
bVar = ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->bVar;
wVar = ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->wVar;
i++;
bVar = ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->bVar;
wVar = ((t_3byte*)(rgVar+sizeof(t_3byte)*i))->wVar;
}