RTFM знает XMega A Manual Rev.H p.216:
19.7 Enabling External Driver Interface
An external drivers interface can be enabled. When this is done the internal TWI drivers with
input filtering and slew rate control are bypassed. The normal I/O pin function is used and the
direction must be configured by the user software. When this mode is enabled an external TWI
compliant tri-state driver is needed for connecting to a TWI bus.
By default port pin 0 (Pn0) and 1 (Pn1) is used for SDA and SCL. The external driver interface
uses port pin 0 to 3 for the signals SDA_IN, SCL_IN, SDA_OUT and SCL_OUT.